Afterward, the authors investigated extra amides to handle the minimal reactivity of four-toluenesulfonamide 35a In this particular reaction. The results showed that phenylsulfonamides 35b that contains electron-deficient substituents created much better yields with the target indazoles 36. Several substituted acetophenone oxime ethers 34 derived from propiophenone, n
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-indazoles 1a–m with distinctive substituted aldehydes 2a–q/benzyl alcohols 5a–e/styrenes 6a–e in as many as 87% yields.
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Comparing aromatic aldehydes with aliphatic aldehydes, the latter were being observed to be less reactive than the previous. A special observation was observed in the current protocol when the volume of carbon atoms greater to four (unbranched and/or branched) while in the aldehydes.7 Compounds 2l–m on response with 1a under the optimized reaction conditions did not furnish C-three acylated two
-indazole scaffold. In see of such antecedents, it was envisioned that the development of the regioselective protocol for indazole N
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